Your Location：Home >Products >Organic Chemistry >1530-32-1

1530-32-1

  • Product NameEthyltriphenylphosphonium Bromide
  • MFC20H20BrP
  • Molecular Weight371.257
  • Purity99%
  • Appearancewhite to off-white crystalline powder
Inquiry

Product Details

Quick Details

  • CasNo： 1530-32-1
  • MF： C20H20BrP
  • Appearance： white to off-white crystalline powder
  • Purity： 99%

Quality Factory Supply Top Purity 99% Ethyltriphenylphosphonium Bromide 1530-32-1 Lowest Price

  • Molecular Formula:C20H20BrP
  • Molecular Weight:371.257
  • Appearance/Colour:white to off-white crystalline powder 
  • Vapor Pressure:0-0.1Pa at 20-25℃ 
  • Melting Point:203-205 °C(lit.) 
  • Boiling Point:240℃[at 101 325 Pa] 
  • Flash Point:200 °C 
  • PSA：13.59000 
  • Density:1.38[at 20℃] 
  • LogP:1.00440 

Ethyltriphenylphosphonium bromide(Cas 1530-32-1) Usage

Chemical Properties

White to off-white crystalline powder

Uses

suzuki reaction

Flammability and Explosibility

Notclassified

Purification Methods

Recrystallise it from H2O and dry it in high vacuum at 100o. IR has bands at 1449, 1431 and 997cm-1 . [Wittig & Wittenberg Justus Liebigs Ann Chem 606 1 1957, Bergmann & Dusza J Org Chem 23 1245 1958, Beilstein 16 IV 982.]

InChI:InChI=1/C20H20BrP/c1-2-22(21,18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h3-17H,2H2,1H3

1530-32-1 Relevant articles

CATALYTIC PHOSPHORYLATION OF POLYFLUOROALKANOLS. 13. SOME AMMONIUM AND PHOSPHONIUM SALTS AS PHOSPHYRYLATION CATALYSTS

Kabachnik, M. I.,Zakharov, L. S.,Kudryatsev, I. Yu.

, p. 2553 - 2556 (1989)

It was shown that it is possible to use ...

Synthesis and coordination chemistry of pentadienyl ligands derived from (1 R)-(-)-myrtenal

Fecker, Ann Christin,Craciun, Bogdan-Florin,Freytag, Matthias,Jones, Peter G.,Walter, Marc D.

, p. 3792 - 3803 (2014)

With the natural product (1R)-(-)-myrten...

Nucleophilic 1,1-Difluoroethylation with Fluorinated Phosphonium Salt

Deng, Zuyong,Liu, Can,Zeng, Xian-Liang,Lin, Jin-Hong,Xiao, Ji-Chang

, p. 12084 - 12090 (2016)

The fluorinated phosphonium salt (Ph3P+C...

β-Amyrin Biosynthesis: The Methyl-30 Group of (3S)-2,3-Oxidosqualene Is More Critical to Its Correct Folding to Generate the Pentacyclic Scaffold than the Methyl-24 Group

Hoshino, Tsutomu,Miyahara, Yuri,Hanaoka, Masaki,Takahashi, Kazunari,Kaneko, Ikki

, p. 15769 - 15784 (2015)

Oxidosqualene cyclases catalyze the tran...

Conformational Control of Initiation Rate in Hoveyda-Grubbs Precatalysts

Gregg, Zackary R.,Griffiths, Justin R.,Diver, Steven T.

, p. 1526 - 1533 (2018)

When the coordinating isopropyl ether of...

Substituted dienes prepared from betulinic acid – Synthesis, cytotoxicity, mechanism of action, and pharmacological parameters

Frydrych, Ivo,Urban, Milan,?arek, Jan,Benická, Sandra,D?ubák, Petr,Gurská, Soňa,Hajdúch, Marián,Kotulová, Jana,Li?ková, Barbora,Olejníková, Denisa,Pokorny, Jan

, (2021/07/28)

A set of new substituted dienes were syn...

Progress toward a Convergent, Asymmetric Synthesis of Jervine

De Jesús Cruz, Pedro,Johnson, Jeffrey S.,Zavesky, Blane P.

supporting information, (2020/04/30)

Progress toward a convergent approach fo...

Isoxazoline derivative and application thereof in agriculture

-

Paragraph 0233; 0237-0238, (2020/11/25)

The invention provides an isoxazoline de...

Visible Light Induced Cyclization to Spirobi[indene] Skeletons from Functionalized Alkylidienecyclopropanes

Li, Quanzhe,Liu, Jiaxin,Shi, Min,Wei, Yin

supporting information, (2020/03/26)

In this paper, we revealed a metal-free ...

1530-32-1 Process route

(diethoxymethyl)benzene
774-48-1

(diethoxymethyl)benzene

triphenylphosphine hydrobromide
6399-81-1

triphenylphosphine hydrobromide

ethyltriphenylphosphonium bromide
1530-32-1

ethyltriphenylphosphonium bromide

benzaldehyde
100-52-7

benzaldehyde

Conditions
Conditions Yield
In dichloromethane; at 50 ℃; for 0.0833333h; Microwave irradiation; Sealed tube;
73%
66%
ethyl bromide
74-96-4

ethyl bromide

triphenylphosphine
603-35-0

triphenylphosphine

ethyltriphenylphosphonium bromide
1530-32-1

ethyltriphenylphosphonium bromide

Conditions
Conditions Yield
for 48h; Heating;
98%
In acetonitrile; Heating;
96.8%
In ethanol; for 21h; Heating;
94.2%
at 100 ℃; for 1h;
91%
In toluene; for 10h; Reflux;
91.8%
In benzene; at 20 ℃; for 4h;
90%
In benzene; at 40 ℃; for 48h;
89.2%
for 120h; Reflux; Inert atmosphere;
87%
In toluene; for 17h; Inert atmosphere; Schlenk technique; Reflux;
84%
In toluene; Reflux;
81%
In toluene; at 70 ℃; for 24h; Inert atmosphere;
79%
In toluene; at 115 ℃; for 16h; Inert atmosphere;
79%
In toluene; at 75 ℃; for 24h;
74%
In toluene; at 100 ℃;
70.5%
In para-xylene; at 110 ℃; for 3h; Inert atmosphere;
63%
In acetonitrile;
In toluene; at 90 ℃; for 24h;
In toluene; for 24h; Reflux;
In toluene; for 8h; Reflux;
8.05 g
for 62h; Schlenk technique; Inert atmosphere; Reflux;
In toluene; for 16h; Reflux;
In acetonitrile; Reflux;
In toluene; at 120 ℃; for 24h;
In 5,5-dimethyl-1,3-cyclohexadiene; at 130 ℃; for 12h;
Reflux;

1530-32-1 Upstream products

  • 74-96-4
    74-96-4

    ethyl bromide

  • 603-35-0
    603-35-0

    triphenylphosphine

  • 774-48-1
    774-48-1

    (diethoxymethyl)benzene

  • 6399-81-1
    6399-81-1

    triphenylphosphine hydrobromide

1530-32-1 Downstream products

  • 61883-35-0
    61883-35-0

    5,5,5-triphenyl-pent-2c-ene

  • 61883-36-1
    61883-36-1

    (E)-pent-3-ene-1,1,1-triyltribenzene

  • 104851-43-6
    104851-43-6

    4-methyl-3-phenyl-pent-2ξ-ene

  • 15055-54-6
    15055-54-6

    (2-hydroxyimino-1-methyl-2-phenyl-ethyl)-triphenyl-phosphonium; bromide

Relevant Products

Copyright © 2024 Shandong Promise New Material Co.,Ltd. ICP NO.:Zhejiang000000