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The synthetic methods for new 2-, 2,2′-,...
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formaldehyd
biphenyl
4,4'-bis(chloromethyl)biphenyl
Conditions | Yield |
---|---|
With
hydrogenchloride; chloroacetic acid;
In
cyclohexane;
at 20 - 40 ℃;
for 6.5h;
Reagent/catalyst;
Time;
Molecular sieve;
Sonication;
Large scale;
|
99.7% |
With
hydrogenchloride;
In
water; methyl cyclohexane;
at 70 ℃;
for 10h;
|
90% |
With
hydrogenchloride;
In
tetrachloromethane; water;
at 65 ℃;
for 20h;
Temperature;
Solvent;
|
89.8% |
With
hydrogenchloride; acetic acid;
at 50 ℃;
for 8h;
Temperature;
Reagent/catalyst;
|
88% |
With
hydrogenchloride; acetic acid;
zinc(II) chloride;
In
tetrachloromethane;
at 50 - 60 ℃;
for 24h;
|
18% |
With
hydrogenchloride;
In
cyclohexane;
at 65 ℃;
for 15h;
Temperature;
|
|
formaldehyd; biphenyl;
With
hydrogenchloride; sulfuryl dichloride; acetic acid; zinc(II) chloride;
In
cyclohexane; water;
for 0.25h;
In
cyclohexane; water;
at 25 ℃;
for 5h;
under 0 Torr;
Further stages;
|
(4,4'-dimethyl-1,1'-biphenyl)
4,4'-bis(chloromethyl)biphenyl
Conditions | Yield |
---|---|
(4,4'-dimethyl-1,1'-biphenyl);
With
sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); 7,7',8,8'-tetracyanoquinodimethane;
In
chlorobenzene;
at 62 - 67 ℃;
for 1.08333h;
Inert atmosphere;
With
sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); 7,7',8,8'-tetracyanoquinodimethane;
In
chlorobenzene;
for 0.833333h;
Temperature;
Reagent/catalyst;
Solvent;
Inert atmosphere;
|
95.3% |
With
chlorine;
In
chlorobenzene;
at 75 ℃;
for 11.5h;
Solvent;
Temperature;
UV-irradiation;
Large scale;
|
94% |
formaldehyd
biphenyl
bis(2-chloromethyl)ether
hydrogenchloride
4,4’-bis(cyanomethyl)-1,1’biphenyl
4,4'-divinyl-biphenyl
biphenyl-4,4'-bis(methyltriphenylphosphonium chloride)
2,2-bis-[4-(4'-chloromethyl-biphenyl-4-ylmethoxy)-phenyl]-indan-1,3-dione
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