1667-10-3

  • Product Name4,4'-Bis(chloromethyl)-1,1'-biphenyl
  • MFC14H12Cl2
  • Molecular Weight251.155
  • Purity99%
  • Appearancewhite to off-white powder
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Product Details

Quick Details

  • CasNo: 1667-10-3
  • MF: C14H12Cl2
  • Appearance: white to off-white powder
  • Purity: 99%

Quality Factory Supply Reliable Quality 4,4'-Bis(chloromethyl)-1,1'-biphenyl 1667-10-3 Reasonable Price

  • Molecular Formula:C14H12Cl2
  • Molecular Weight:251.155
  • Appearance/Colour:white to off-white powder 
  • Vapor Pressure:4.6Pa at 20℃ 
  • Melting Point:126 °C (dec.)(lit.) 
  • Boiling Point:380 °C at 760 mmHg 
  • Flash Point:196.3 °C 
  • PSA:0.00000 
  • Density:1.195 g/cm3 
  • LogP:4.83120 

1667-10-3 Relevant articles

Synthesis, antimicrobial and antifungal activity of double quaternary ammonium salts of biphenyls

Ol'Khovik,Matveienko, Yu. V.,Vasilevskii,Kalechits,Zheldakova

, p. 329 - 335 (2013)

The synthetic methods for new 2-, 2,2′-,...

Production process of 4,4'-dichloromethylbiphenyl

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Paragraph 0018; 0029-0080, (2021/03/31)

The invention relates to a production pr...

Method for preparing biphenyl benzyl dichloride through photocatalytic chlorination

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Paragraph 0041-0049, (2020/04/06)

The invention discloses a method for pre...

Preparation method of 4,4'-dichloromethylbiphenyl

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Paragraph 0021-0044, (2019/08/01)

The invention discloses a preparation me...

Catalysis preparation process for 4,4'-dichloro methyl biphenyl

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Page/Page column 4-6, (2017/08/28)

The invention discloses a catalysis prep...

1667-10-3 Process route

formaldehyd
50-00-0,30525-89-4,61233-19-0

formaldehyd

biphenyl
92-52-4,1594-86-1

biphenyl

4,4'-bis(chloromethyl)biphenyl
1667-10-3

4,4'-bis(chloromethyl)biphenyl

Conditions
Conditions Yield
With hydrogenchloride; chloroacetic acid; In cyclohexane; at 20 - 40 ℃; for 6.5h; Reagent/catalyst; Time; Molecular sieve; Sonication; Large scale;
99.7%
With hydrogenchloride; In water; methyl cyclohexane; at 70 ℃; for 10h;
90%
With hydrogenchloride; In tetrachloromethane; water; at 65 ℃; for 20h; Temperature; Solvent;
89.8%
With hydrogenchloride; acetic acid; at 50 ℃; for 8h; Temperature; Reagent/catalyst;
88%
With hydrogenchloride; acetic acid; zinc(II) chloride; In tetrachloromethane; at 50 - 60 ℃; for 24h;
18%
With hydrogenchloride; In cyclohexane; at 65 ℃; for 15h; Temperature;
formaldehyd; biphenyl; With hydrogenchloride; sulfuryl dichloride; acetic acid; zinc(II) chloride; In cyclohexane; water; for 0.25h;
In cyclohexane; water; at 25 ℃; for 5h; under 0 Torr; Further stages;
(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

4,4'-bis(chloromethyl)biphenyl
1667-10-3

4,4'-bis(chloromethyl)biphenyl

Conditions
Conditions Yield
(4,4'-dimethyl-1,1'-biphenyl); With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); 7,7',8,8'-tetracyanoquinodimethane; In chlorobenzene; at 62 - 67 ℃; for 1.08333h; Inert atmosphere;
With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); 7,7',8,8'-tetracyanoquinodimethane; In chlorobenzene; for 0.833333h; Temperature; Reagent/catalyst; Solvent; Inert atmosphere;
95.3%
With chlorine; In chlorobenzene; at 75 ℃; for 11.5h; Solvent; Temperature; UV-irradiation; Large scale;
94%

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